On the rigidity of a hard sphere glass near random close packing
نویسندگان
چکیده
– We study theoretically and numerically the microscopic cause of the rigidity of hard sphere glasses near their maximum packing. We show that, after coarse-graining over time, the hard sphere interaction can be described by an effective potential which is exactly logarithmic at the random close packing φc. This allows to define normal modes, and to apply recent results valid for elastic networks: rigidity is a non-local property of the packing geometry, and is characterized by some length scale l∗ which diverges at φc [1, 2]. We compute the scaling of the bulk and shear moduli near φc, and speculate on the possible implications of these results for the glass transition. Hard spheres present a glass phase between φ0, where the glass transition occurs and structural relaxation becomes unobservable, and φc where the pressure p diverges. In this region this system is solid and resists to shear on any measurable time scales. Although a large amount of works focused on the super-cooled liquid, the glass itself received less attention. In particular, there is no undoubted microscopic theory to explain its mechanical properties and its rigidity. In the cage-escape picture [3], the cage formed by the neighboring particles tighten as φ increases, and the typical time for a particle to escape its cage grows and eventually diverges. Nevertheless, Maxwell showed that the stability against collective motions of particles is more demanding than against individual particle displacements: in particular z = d+ 1 inter-particle contacts are sufficient to pin one particle in d dimensions, whereas zc = 2d contacts in average are required to guarantee mechanical stability [4]. Thus considering a priori rigidity as a local property may be inappropriate. Recently several works [1, 2, 5, 6, 8, 7] studied the mechanical properties of weaklyconnected elastic networks with an average contacts number —the coordination number— z close to the critical value zc = 2d, such as those encountered for athermal repulsive shortrange particles above φc [5, 6]. In particular it was shown that (i) these systems present an
منابع مشابه
Pushing the glass transition towards random close packing using self-propelled hard spheres.
Although the concept of random close packing with an almost universal packing fraction of approximately 0.64 for hard spheres was introduced more than half a century ago, there are still ongoing debates. The main difficulty in searching the densest packing is that states with packing fractions beyond the glass transition at approximately 0.58 are inherently non-equilibrium systems, where the dy...
متن کاملOn the jamming phase diagram for frictionless hard-sphere packings.
We computer-generated monodisperse and polydisperse frictionless hard-sphere packings of 10(4) particles with log-normal particle diameter distributions in a wide range of packing densities φ (for monodisperse packings φ = 0.46-0.72). We equilibrated these packings and searched for their inherent structures, which for hard spheres we refer to as closest jammed configurations. We found that the ...
متن کاملPacking hard spheres with short-range attraction in infinite dimension: phase structure and algorithmic implications
We study, via the replica method of disordered systems, the packing problem of hard-spheres with a square-well attractive potential when the space dimensionality, d, becomes infinitely large. The phase diagram of the system exhibits reentrancy of the liquid-glass transition line, two distinct glass states and a glass-to-glass transition, much similar to what has been previously obtained by Mode...
متن کاملWhy is random close packing reproducible?
We link the thermodynamics of colloidal suspensions to the statistics of regular and random packings. Random close packing has defied a rigorous definition yet, in three dimensions, there is near universal agreement on the volume fraction at which it occurs. We conjecture that the common value of phi{rcp} approximately 0.64 arises from a divergence in the rate at which accessible states disappe...
متن کاملar X iv : c on d - m at / 0 60 15 73 v 1 2 5 Ja n 20 06 Amorphous packings of hard spheres in large space dimension
In a recent paper we derived an expression for the replicated free energy of a liquid of hard spheres based on the HNC free energy functional. An approximate equation of state for the glass and an estimate of the random close packing density were obtained in d = 3. Here we show that the HNC approximation is not needed: the same expression can be obtained from the full diagrammatic expansion of ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2008